GROUP OF THE DESIGN AND FINE SYNTHESIS OF
INORGANIC PHASES WITH UNUSUAL ELECTROPHYSICAL PROPERTIES
Inorganic Synthesis Laboratory, Inorganic chemistry division, Department
of Chemistry, MSU
GROUP STAFF
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Ph.D. Associate Prof. |
Ph.D. S Associate Prof. |
POSTGRADUATE STUDENTS
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Oksana P. Grigor'eva
(Department of Chemistry) supervised by VAD |
Contact V.A. Dolgikh
STUDENTS
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(Department
of Material Sciences) supervised by PSB and Dr E.S. Koslyakova
from Department of Physics |
Dissertations & Diploma projects
PICTURES
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Alisher F. Murtazoev with Prof Popovkin B.A. prize certificate
(2023) |
Group Photo (approx end of
1992)
RESEARCH
ACTIVITIES
Determination of the correlations between composition,
structure ferroelectric, ion-conducting and nonlinear optic properties of
crystals as the scientific base for design and synthesis of inorganic compounds
with required properties.
MAIN OBJECTS UNDER INVESTIGATION IN THE
RECENT YEARS
Complex tellurites and selenites
of bismuth and rare earth elements (REE), complex oxohalogenides
and oxochalkogenides.
Large family of layered oxyhalogeniges
of Bi(REE)-Te belonging to a
new type was discovered and investigated. This family has a high percentage of
compounds with noncentrosymmetric structures. Among
them the phases were found having high nonlinear optic parameters and unique
combination of piezoelectric and pyroelectric parameters advantageous for
pyroelectric applications.
The correlations between the composition and the structure were determined for
the phases in this group.
With the help of planned heterovalent substitution of
Bi or REE atoms in their fluorite-like oxofluorides, new anion-conducting
phases with wide homogenity regions were obtained.
The correlation between nonstoichiometry and
transport characteristics of these solid solutions were determined.
Current interests include design, synthesis, crystallographic and SHG
characterization of new layered and inorganic open framework phases.
Research highlights
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BiOCuSe |
α--BiSeO3Cl |
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SrTeO3 |
MNd10(SeO3)12Cl8
(M=Ca, Sr) |
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COLLABORATIONS
Prof.
P. Lightfoot in the School of Chemistry at the University of
St Andrews,
Prof. Dr.
rer. nat. Michael Ruck Anorganische Chemie der TU Dresden,
Germany
Professor
Alain Tressaud Research Director at ICMCB-CNRS,
University Bordeaux 1 (France)
CURRENT PROJECTS:
FINISHED PROJECTS:
Russian Science Foundation 23-23-00205 Synthesis of complex chalcogenite-chalcogenates and chalcogenite-nitrates - substances with promising low-dimensional magnetic properties Supervisor P.S. Berdonosov
RFBR 14-03-00604 Design and targeted synthesis of novel hybrid inorganic phases - salt inclusion solids Supervisor V.A. Dolgikh
RFBR 11-03-00776 The synthesis concept and targeted synthesis of inorganic crystal phases with structures based on open framework 2011-2013 Supervisor V.A. Dolgikh
RFBR Royal Society UK 12-03-92604-KO-a A Crystal-chemical Approach to New Frustrated Magnets 2012-2013 Supervisor V.A. Dolgikh
RFBR 12-03-00665 Directed synthesis of low dimensional d-metal complex selenite-halides as possible frustrated magnets 2012-2014 Supervisor P.S. BerdonosovRFBR 09-03-00799 Synthesis of the complex s-/d-metals,Bi/d-metal selenates(IV) halides and tellurates(IV) halides with noncentrosymmetrical structures 2009-2011 Supervisor P.S. Berdonosov
RFBR 09-03-01064 Development and application of modular approach to design and synthesis of complex inorganic layered perovskites 2009-2011 Supervisor D.O. CharkinRFBR 08-03-00548 The crystal chemistry approach to the design and targeted synthesis of new open-framework inorganic phases 2008-2010 Supervisor V.A. Dolgikh
USSR patent 1715712 V.A. Dolgikh, S.Yu. Stefanovich, B.A. Popovkin, L.N. Kholodkovskaya (Russian)
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2025
2024
CrystEngComm, 2024,26, 5599-5606
Grigorieva O.P., T.B.,
Berdonosov P.S., Charkin D.O., Gippius A.A.1,2, Tkachev A.V.,
Kravchenko E.A., Dolgikh V.A., Lyssenko K.A. Samarium hydrogen iodate, Sm(IO3)3·HIO3: synthesis
and characterization // J. Structural Chemistry (Zhurnal
Strukturnoi Khimii) v.65,
№10, 2024, https://doi.org/10.26902/JSC_id133264
Grigoriy Pashkov, Maria Markina, Konstantin Lyssenko, Peter Berdonosov,
Synthesis, Crystal Structure, and Thermodynamic Properties of Two New Selenate
Chlorides: M2Cu(SeO4)Cl2 with M = K and Rb //
Materials Chemistry and Physics, Volume 319, 1 June 2024, 129367 https://doi.org/10.1016/j.matchemphys.2024.129367
M.M. Markina, P.S. Berdonosov, T.M. Vasilchikova, K.V. Zakharov, A.F.
Murtazoev, V.A. Dolgikh, A.V. Moskin, V.N. Glazkov, A.I. Smirnov, A.N. Vasiliev
Static and resonant properties of decorated square kagom'e lattice KCu7(TeO4)(SO4)5Cl
// Materials Chemistry and Physics, Volume 319, 1 June 2024, 129348 https://doi.org/10.1016/j.matchemphys.2024.129348
New iodate fluoride Rb2Ce(IO3)5F
with nonlinear optical properties// Dalton Trans., 2024, 53,
7367-7375 https://doi.org/10.1039/D4DT00431K
Journal
of Magnetism and Magnetic Materials, 2024, 171786, https://doi.org/10.1016/j.jmmm.2024.171786
2023
Cascade of Magnetic Phase Transitions
and 1/3-Magnetization Plateau in Selenite-Selenate Co3(SeO3)(SeO4)(OH)2
with Layers of a Kagomé-like Co2+ Ion Arrangement: Importance of
Identifying a Correct Spin Lattice // Dalton Trans.,
2023,52, 9664-9672 https://doi.org/10.1039/D3DT01620J
Alisher
F Murtazoev, Peter S Berdonosov, Konstantin Lyssenko, Valery Dolgikh, Zlata
Victorovna Pchelkina, Konstantin Zakharov, Mikhael Geidorf, Tatyana M.
Vasilchikova, Olga S. Volkova and Alexander Vasiliev Anhydrous
copper tellurite-disulfate Cu3TeO3(SO4)2
featuring coexistence of spin singlets and long-range antiferromagnetic order
// Dalton Trans., 2023,52,
9247-9253 https://doi.org/10.1039/D3DT01290E
Alisher
F Murtazoev, Konstantin A Lyssenko, Maria M. Markina, Valery A. Dolgikh, Alexander N. Vasiliev, Peter Berdonosov New
Nabokoite-Like Phases ACu7TeO4(SO4)5Cl
(A = Na, K, Rb, Cs) with Decorated and Distorted Square Kagome Lattices //
ChemPhysChem 2023, e202300111. https://doi.org/10.1002/cphc.202300111
Olga S. Volkova, Peter S. Berdonosov, Irina K. Shamova, Badiur Rahaman,
Asif Iqbal, Tanusri Saha-Dasgupta, Alexander N. Vasiliev, Thermal and magnetic
properties of Cu4O(SeO3)3 composed by
ferrimagnetic O2Cu6 units of edge-sharing OCu4
tetrahedra // J. Alloys and Comp. 956 (2023) 170346, https://doi.org/10.1016/j.jallcom.2023.170346
A. F. Murtazoev, P. S. Berdonosov, S. M. Aksenov, A. N. Kuznetsov, V. A.
Dolgikh, Y. V. Nelyubina and S. Merlino Polytypism of Ln(SeO3)(HSeO3)·2H2O
compounds: synthesis and crystal structure of the first monoclinic modification
of Nd(SeO3)(HSeO3)·2H2O, DFT calculations and order/disorder description
// Acta Cryst. (2023). B79 https://doi.org/10.1107/S2052520622012227
Sergei Klimin, Peter Berdonosov, Elena Kuznetsova Magnetic Ordering and
Interplay between the Magnetic and Charge Subsystems in New Francisite-Analog
Cu3Dy(SeO3)2O2Cl as Studied by the
Spectroscopy of Kramers Doublets // Phys. Status Solidi RRL 2023, 2200460 https://doi.org/10.1002/pssr.202200460
Maria Markina, Tatyana Vasilchikova,
Elena Kuznetsova, Peter Berdonosov, Andrey Olenev, Seung Hwan Chung, Hyun-Joo
Koo, Myung-Hwan Whangbo, and Alexander Vasiliev Preparation and
Characterization of Francisite Solid Solutions Cu3Bi(Se1-xTexO3)2O2Br
(x = 0-1): Possibility for Francisites as // Chem. Mater. 2023, 35, 511-520
Starting Materials for Oxide van der Waals Ferromagnets DOI: https://doi.org/10.1021/acs.chemmater.2c02865
Dmitri O. Charkin, Vasili Yu.
Grishaev, Artem S. Borisov, Pavel A. Chachin, Evgeni V. Nazarchuk, Oleg I.
Siidra A nonpolar bond to hydrogen vs. lone pair: Incorporation of HPO32-
and SeEO32- into a lead perrhenate framework // J. of
Solid State Chemistry 318 (2023) 123706 DOI: https://doi.org/10.1016/j.jssc.2022.123706
2022
Dmitri O. Charkin, Valeri A. Dolgikh,
Timofey A. Omelchenko, Yulia A. Vaitieva, Sergey N. Volkov, Dina V. Deyneko and
Sergey M. Aksenov Symmetry Analysis of the Complex Polytypism of Layered
Rare-Earth Tellurites and Related Selenites: The Case of Introducing Transition
Metals. // Symmetry 2022, 14, 2087. DOI: https://doi.org/10.3390/sym14102087
Markina M, Zakharov K, Ovchenkov Y,
Pashkov G, Lyssenko K, Berdonosov P, Pchelkina Z, Vasiliev A.
Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing
Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions.
Materials. 2022; 15(21):7860. DOI: https://doi.org/10.3390/ma15217860
A. N. Vasiliev, P.S. Berdonosov, E.S.
Kozlyakova, O. V. Maximova, A. F. Murtazoev, V. A. Dolgikh, K. A. Lyssenko, Z.
V. Pchelkina, D. I. Gorbunov, S. H. Chung, H.-J. Koof, M.-H. Whangbo
Observation of a 1/3 magnetization plateau in Pb2Cu10O4(SeO3)4Cl7
arising from (Cu2+)7 clusters of corner-sharing (Cu2+)4
tetrahedra // Dalton Trans., 2022,51, 15017-15021 DOI: DOI:
10.1039/D2DT02316D
S. Spachmann, P. Berdonosov, M.
Markina, A. Vasiliev & R. Klingeler Linear magnetoelastic coupling and
magnetic phase diagrams of the buckled kagome antiferromagnet Cu3Bi(SeO3)2O2Cl
// Scientific Reports (2022) 12:7383 DOI: https://doi.org/10.1038/s41598-022-11368-5
Dmitri O. Charkin, Sergey N. Volkov,
Valeri A. Dolgikh, Sergey M. Aksenov Potassium rare-earth tellurite chlorides:
A new branch from the old root // Solid State Sciences, 2022, 1, 39-48 DOI 10.1016/j.solidstatesciences.2022.106895
Alisher F.Murtazoev, Sergey G.
Dorofeev, Alexey O.Gudovannyy, Konstantin A.Lyssenko, Valery A.Dolgikh, Peter
S.Berdonosov New europium selenate (Vi) tetrahydrate: Crystal structure and
optical properties // Journal of Solid State Chemistry Volume 311, July 2022,
123090 DOI 10.1016/j.jssc.2022.123090
Климин С.А., Кузнецова Е.С.,
Бердоносов П.С. Штарковские уровни иона SmБ3+ в низкоразмерном
магнетике Cu3Sm(SeO3)2O2Cl //
Оптика и спектроскопия, 2022, 1, 39-48 DOI 10.21883/OS.2022.01.51888.37-21
Новикова Н.Н., Яковлев В.А., Кузнецова Е.С., Бердоносов П.С. Климин С.А.
Химическое сжатие, структурная нестабильность и ИК-активные фононы в ряду
редкоземельных аналогов францисита Cu3RE(SeO3)2O2Cl //
Оптика и спектроскопия 130(2022) 49-58 DOI: 10.21883/OS.2022.01.51889.22-21
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Last updated 14.12.2020