GROUP OF THE DESIGN AND FINE SYNTHESIS OF INORGANIC PHASES WITH UNUSUAL ELECTROPHYSICAL PROPERTIES

Inorganic Synthesis Laboratory, Inorganic chemistry division, Department of Chemistry, MSU

Group leader Dr.Sc., Prof. Dolgikh V.A. Phone: 007-(495)-939-3504 email dolgikh *

GROUP STAFF

Ph.D. Associate Prof. Berdonosov P.S. berdonosov*

Ph.D. S Associate Prof. Charkin D.O. charkin*

POSTGRADUATE STUDENTS

Murtrazoev Alisher (Department of Materials Science) supervised by PSB & VAD alisher*

Oksana P. Grigor'eva (Department of Chemistry) supervised by VAD grigoreva.op*

Contact V.A. Dolgikh

STUDENTS

Gregori Pashkov (Department of Chemistry) supervised by PSB

Nikita Astakhov (Department of Material Sciences) supervised by PSB and Dr E.S. Koslyakova from Department of Physics

Miryam Belareva (Department of Chemistry) supervised by PSB

GROUP ALUMNI

Dissertations & Diploma projects

PICTURES

	Alisher F. Murtazoev with Prof Popovkin B.A. prize certificate (2023)

Group Photo (approx end of 1992)

Group Photo (2004)	Group Photo (May 2005)	Group Photo (May 2006)	Vladimir A. Prituzhalov PhD council pictures (2008)
Group Photo (June 2010)	B.V. Egorova diploma (June 2011)	St Andrews visitors in June 2013	May - June 2014
Some May-June 2017 Pics 16th European Conference on Solid State Chemistry July 2017 Glasgow	Elena S. Kuznetsova PhD council pictures (Nov 2018)	Prof Valery A. Dolgikh 80th birthday in the lab(Jan 2022)	Group photo 2022 (Nov 2022)
NUST MISIS seminar 2023

RESEARCH ACTIVITIES

Determination of the correlations between composition, structure ferroelectric, ion-conducting and nonlinear optic properties of crystals as the scientific base for design and synthesis of inorganic compounds with required properties.

MAIN OBJECTS UNDER INVESTIGATION IN THE RECENT YEARS

Complex tellurites and selenites of bismuth and rare earth elements (REE), complex oxohalogenides and oxochalkogenides.

Large family of layered oxyhalogeniges of Bi(REE)-Te belonging to a new type was discovered and investigated. This family has a high percentage of compounds with noncentrosymmetric structures. Among them the phases were found having high nonlinear optic parameters and unique combination of piezoelectric and pyroelectric parameters advantageous for pyroelectric applications.
The correlations between the composition and the structure were determined for the phases in this group.
With the help of planned heterovalent substitution of Bi or REE atoms in their fluorite-like oxofluorides, new anion-conducting phases with wide homogenity regions were obtained. The correlation between nonstoichiometry and transport characteristics of these solid solutions were determined.
Current interests include design, synthesis, crystallographic and SHG characterization of new layered and inorganic open framework phases.

Research highlights

BiOCuSe First Bi compound with LnOTX (Ln - lanthanide, Bi; T = Cu, Ag; X = S, Se, Te, T = Fe, Ni, X = P, As) structure	α--BiSeO3Cl First Selenate(IV) chloride of Bi (III) with NCS structure
SrTeO3 Ferroelectric with unusual properties and complex structure	MNd10(SeO3)12Cl8 (M=Ca, Sr) First Alkaline Earths representatives of M11(SeO3)12Xx phase family

COLLABORATIONS

Prof. P. Lightfoot  in the School of Chemistry  at the University of St Andrews, UK

Prof. Dr. rer. nat. Michael Ruck Anorganische Chemie der TU Dresden,  Germany

Professor Alain Tressaud Research Director at ICMCB-CNRS, University Bordeaux 1 (France)

CURRENT PROJECTS:

Russian Science Foundation 23-23-00205 Synthesis of complex chalcogenite-chalcogenates and chalcogenite-nitrates - substances with promising low-dimensional magnetic properties Supervisor P.S. Berdonosov

FINISHED PROJECTS:

RFBR 14-03-00604 Design and targeted synthesis of novel hybrid inorganic phases - salt inclusion solids Supervisor V.A. Dolgikh

RFBR 11-03-00776 The synthesis concept and targeted synthesis of inorganic crystal phases with structures based on open framework 2011-2013 Supervisor V.A. Dolgikh
RFBR Royal Society UK 12-03-92604-KO-a A Crystal-chemical Approach to New Frustrated Magnets 2012-2013 Supervisor V.A. Dolgikh  
RFBR 12-03-00665 Directed synthesis of low dimensional d-metal complex selenite-halides as possible frustrated magnets 2012-2014 Supervisor P.S. Berdonosov

RFBR 09-03-00799 Synthesis of the complex s-/d-metals,Bi/d-metal selenates(IV) halides and tellurates(IV) halides with noncentrosymmetrical structures 2009-2011 Supervisor P.S. Berdonosov
RFBR 09-03-01064 Development and application of modular approach to design and synthesis of complex inorganic layered perovskites 2009-2011 Supervisor D.O. Charkin

RFBR 08-03-00548 The crystal chemistry approach to the design and targeted synthesis of new open-framework inorganic phases 2008-2010 Supervisor V.A. Dolgikh

PUBLICATIONS

USSR patent 1715712 V.A. Dolgikh, S.Yu. Stefanovich, B.A. Popovkin, L.N. Kholodkovskaya (Russian)

Some papers from XX century
2000	2001	2002	2003
2004	2005	2006	2007
2008	2009	2010	2011
2012	2013	2014	2015
2016	2017	2018	2019
2020

2024

Grigoriy Pashkov, Maria Markina, Konstantin Lyssenko, Peter Berdonosov, Synthesis, Crystal Structure, and Thermodynamic Properties of Two New Selenate Chlorides: M₂Cu(SeO₄)Cl₂ with M = K and Rb // Materials Chemistry and Physics, 2024, 129367, Accepted https://doi.org/10.1016/j.matchemphys.2024.129367

M.M. Markina, P.S. Berdonosov, T.M. Vasilchikova, K.V. Zakharov, A.F. Murtazoev, V.A. Dolgikh, A.V. Moskin, V.N. Glazkov, A.I. Smirnov, A.N. Vasiliev Static and resonant properties of decorated square kagom'e lattice KCu₇(TeO₄)(SO₄)₅Cl // Materials Chemistry and Physics, 2024, 129348 Accepted https://doi.org/10.1016/j.matchemphys.2024.129348

Oksana Grigoreva, Tatiana Shatalova, Alexey N. Kuznetsov, Peter S Berdonosov, Sergey Stefanovich, Konstantin Lyssenko and Valery Dolgikh New iodate fluoride Rb₂Ce(IO₃)₅F with nonlinear optical properties // Dalton Trans., 2024, Accepted https://doi.org/10.1039/D4DT00431K

Ya.V. Rebrov, V.N. Glazkov, A.F. Murtazoev, V.A. Dolgikh, P.S. Berdonosov  High-frequency dielectric anomalies in a highly frustrated square kagomé lattice nabokoite family compounds ACu₇(TeO₄)(SO₄)₅Cl (A=Na, K, Rb, Cs)// Journal of Magnetism and Magnetic Materials, 2024, 171786, https://doi.org/10.1016/j.jmmm.2024.171786

2023

Alisher F Murtazoev,   Peter S Berdonosov,   Konstantin Lyssenko,   Valery Dolgikh,   Mikhael Geidorf,   Olga S. Volkova,   Hyun-Joo Koo,   Mike Whangbo  and  Alexander Vasiliev   Cascade of Magnetic Phase Transitions and 1/3-Magnetization Plateau in Selenite-Selenate Co₃(SeO₃)(SeO₄)(OH)2 with Layers of a Kagomé-like Co2+ Ion Arrangement: Importance of Identifying a Correct Spin Lattice // Dalton Trans., 2023,52, 9664-9672 https://doi.org/10.1039/D3DT01620J

Alisher F Murtazoev, Peter S Berdonosov, Konstantin Lyssenko, Valery Dolgikh, Zlata Victorovna Pchelkina, Konstantin Zakharov, Mikhael Geidorf, Tatyana M. Vasilchikova, Olga S. Volkova and Alexander Vasiliev Anhydrous copper tellurite-disulfate Cu₃TeO₃(SO₄)₂ featuring coexistence of spin singlets and long-range antiferromagnetic order // Dalton Trans., 2023,52, 9247-9253 https://doi.org/10.1039/D3DT01290E

Alisher F Murtazoev, Konstantin A Lyssenko, Maria M. Markina, Valery A. Dolgikh, Alexander N. Vasiliev, Peter Berdonosov New Nabokoite-Like Phases ACu₇TeO₄(SO₄)₅Cl (A = Na, K, Rb, Cs) with Decorated and Distorted Square Kagome Lattices // ChemPhysChem 2023, e202300111. https://doi.org/10.1002/cphc.202300111

Olga S. Volkova, Peter S. Berdonosov, Irina K. Shamova, Badiur Rahaman, Asif Iqbal, Tanusri Saha-Dasgupta, Alexander N. Vasiliev, Thermal and magnetic properties of Cu₄O(SeO₃)₃ composed by ferrimagnetic O₂Cu₆ units of edge-sharing OCu₄ tetrahedra // J. Alloys and Comp. 956 (2023) 170346, https://doi.org/10.1016/j.jallcom.2023.170346

A. F. Murtazoev, P. S. Berdonosov, S. M. Aksenov, A. N. Kuznetsov, V. A. Dolgikh, Y. V. Nelyubina and S. Merlino Polytypism of Ln(SeO₃)(HSeO₃)·2H₂O compounds: synthesis and crystal structure of the first monoclinic modification of Nd(SeO₃)(HSeO₃)·2H₂O, DFT calculations and order/disorder description // Acta Cryst. (2023). B79 https://doi.org/10.1107/S2052520622012227

Sergei Klimin, Peter Berdonosov, Elena Kuznetsova Magnetic Ordering and Interplay between the Magnetic and Charge Subsystems in New Francisite-Analog Cu₃Dy(SeO₃)₂O₂Cl as Studied by the Spectroscopy of Kramers Doublets // Phys. Status Solidi RRL 2023, 2200460 https://doi.org/10.1002/pssr.202200460

Maria Markina, Tatyana Vasilchikova, Elena Kuznetsova, Peter Berdonosov, Andrey Olenev, Seung Hwan Chung, Hyun-Joo Koo, Myung-Hwan Whangbo, and Alexander Vasiliev Preparation and Characterization of Francisite Solid Solutions Cu3Bi(Se_1-xTexO₃)₂O₂Br (x = 0-1): Possibility for Francisites as // Chem. Mater. 2023, 35, 511-520 Starting Materials for Oxide van der Waals Ferromagnets DOI: https://doi.org/10.1021/acs.chemmater.2c02865

Dmitri O. Charkin, Vasili Yu. Grishaev, Artem S. Borisov, Pavel A. Chachin, Evgeni V. Nazarchuk, Oleg I. Siidra A nonpolar bond to hydrogen vs. lone pair: Incorporation of HPO₃^2- and SeEO₃^2- into a lead perrhenate framework // J. of Solid State Chemistry 318 (2023) 123706 DOI: https://doi.org/10.1016/j.jssc.2022.123706

2022

Dmitri O. Charkin, Valeri A. Dolgikh, Timofey A. Omelchenko, Yulia A. Vaitieva, Sergey N. Volkov, Dina V. Deyneko and Sergey M. Aksenov Symmetry Analysis of the Complex Polytypism of Layered Rare-Earth Tellurites and Related Selenites: The Case of Introducing Transition Metals. // Symmetry 2022, 14, 2087. DOI: https://doi.org/10.3390/sym14102087

Markina M, Zakharov K, Ovchenkov Y, Pashkov G, Lyssenko K, Berdonosov P, Pchelkina Z, Vasiliev A. Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions. Materials. 2022; 15(21):7860. DOI: https://doi.org/10.3390/ma15217860

A. N. Vasiliev, P.S. Berdonosov, E.S. Kozlyakova, O. V. Maximova, A. F. Murtazoev, V. A. Dolgikh, K. A. Lyssenko, Z. V. Pchelkina, D. I. Gorbunov, S. H. Chung, H.-J. Koof, M.-H. Whangbo Observation of a 1/3 magnetization plateau in Pb₂Cu₁₀O₄(SeO₃)₄Cl₇ arising from (Cu²⁺)₇ clusters of corner-sharing (Cu²⁺)₄ tetrahedra // Dalton Trans., 2022,51, 15017-15021 DOI: DOI: 10.1039/D2DT02316D

S. Spachmann, P. Berdonosov, M. Markina, A. Vasiliev & R. Klingeler Linear magnetoelastic coupling and magnetic phase diagrams of the buckled kagome antiferromagnet Cu₃Bi(SeO₃)₂O₂Cl // Scientific Reports (2022) 12:7383 DOI: https://doi.org/10.1038/s41598-022-11368-5

Dmitri O. Charkin, Sergey N. Volkov, Valeri A. Dolgikh, Sergey M. Aksenov Potassium rare-earth tellurite chlorides: A new branch from the old root // Solid State Sciences, 2022, 1, 39-48 DOI 10.1016/j.solidstatesciences.2022.106895

Alisher F.Murtazoev, Sergey G. Dorofeev, Alexey O.Gudovannyy, Konstantin A.Lyssenko, Valery A.Dolgikh, Peter S.Berdonosov New europium selenate (Vi) tetrahydrate: Crystal structure and optical properties // Journal of Solid State Chemistry Volume 311, July 2022, 123090 DOI 10.1016/j.jssc.2022.123090

Климин С.А., Кузнецова Е.С., Бердоносов П.С. Штарковские уровни иона SmБ³⁺ в низкоразмерном магнетике Cu₃Sm(SeO₃)₂O₂Cl // Оптика и спектроскопия, 2022, 1, 39-48 DOI 10.21883/OS.2022.01.51888.37-21

Новикова Н.Н., Яковлев В.А., Кузнецова Е.С., Бердоносов П.С. Климин С.А. Химическое сжатие, структурная нестабильность и ИК-активные фононы в ряду редкоземельных аналогов францисита Cu₃RE(SeO₃)₂O₂Cl // Оптика и спектроскопия 130(2022) 49-58 DOI: 10.21883/OS.2022.01.51889.22-21

2021

Kazuhiro Nawa, Maxim Avdeev, Peter Berdonosov, Alexey Sobolev, Igor Presniakov, Alena Aslandukova, Ekaterina Kozlyakova, Alexander Vasiliev, Igor Shchetinin, Taku J. Sato Magnetic structure study of the sawtooth chain antiferromagnet Fe₂Se₂O₇ // Sci Rep 11, 24049 (2021). DOI:10.1038/s41598-021-03058-5a>

S. A. Klimin, P. S. Berdonosov, E. S. Kuznetsova Quasi-doublets of non-Kramers Ho3+ ion and magnetic ordering of holmium francisite-analog Cu3Ho(SeO₃)₂O₂Cl // Low Temperature Physics 47(12), 1022–1029 (2021) DOI: 10.1063/10.0007075

K. Denisova, P. Lemmens, D. Wulferding, P. Berdonosov, V. Dolgikh, A. Murtazoev, E. Kozlyakova, O. Maximova, A. Vasiliev, I. Shchetinin, F. Dolgushin, A. Iqbal, B. Rahaman, T. Saha-Dasgupta, Cu₉O₂(SeO₃)₄Cl₆ revisited: crystal structure, Raman scattering and first-principles calculations // Journal of Alloys and Compounds, Volume 894, 2022, 162291, DOI: 10.1016/j.jallcom.2021.162291

Alisher F. Murtazoev, Peter S. Berdonosov, Victor A. Tafeenko, Valery A. Dolgikh, Igor L. Danilovich, Zlata V. Pchelkina, Alexander N. Vasiliev Cadmium copper selenite chloride, CdCu₂(SeO₃)₂Cl₂, an insulating spin gap system // Journal of Solid State Chemistry, Volume 303, 2021, 122518, DOI: 10.1016/j.jssc.2021.122518

Kozlyakova, E.S., Moskin, A.V., Berdonosov, P.S., V. V. Gapontsev, S. V. Streltsov, M. Uhlarz, S. Spachmann, A. ElGhandour, R. Klingeler, A. N. Vasiliev Quasi-1D XY antiferromagnet Sr₂Ni(SeO₃)₂Cl₂ at Sakai-Takahashi phase diagram. // Sci Rep 11, 15002 (2021). DOI: 10.1038/s41598-021-94390-3

S. A. Klimin, P. S. Berdonosov, E. S. Kuznetsova Optical Spectroscopy of Kramers Doublets of an Er3+ Ion in a Two-Dimensional Frustrated Magnetic Cu₃Er(SeO₃)₂O₂Cl // Optics and Spectroscopy, 2021, Vol. 129, No. 1, pp. 47–50 DOI: 10.1134/S0030400X21010094

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Last updated 14.12.2020