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Laboratories: Inorganic Materials SciencesChemistry of Coordination Compounds
 Diagnostics of Inorganic Materials Inorganic Synthesis
 Inorganic CrystallochemistryChemistry and Physics of Semiconductor Materials
Synthesis and Investigation of Metal Alcoholates


Headed by N.Ya.Turova(Senior Researcher, PhD)



The development of optimum chemical and electrochemical synthetic techniques for obtaining mono- and bimetallic transition metal alcoholates. The investigation of their physico-chemical and structural characteristics taking into the consideration possible inhomogeneity of molecular content of certain products, as well as micro-impurities of oxo-groups (formed as the result of spontaneous hydrolysis, oxidation, or ether elimination processes). Optimization of the preparation technique for multicomponent alcoholate solutions, utilized in sol-gel process of synthesis of complex oxide-based materials for the needs of modern technology.

Selected Publications for the Period 1998-2002.

  • N.Ya.Turova, E.P.Turevskaya, M.I. Yanovskaya, A.I. Yanovsky et al. Physicochemical approach to the stusies of metal alkoxides, Polyhedron, 1998, 17, 899.
  • V.G. Kessler, A.N. Panov, N.Ya Turova et al. Anodic oxidation of Mo and W in alcohols: isolation and X-ray single-crystal study of side products, J. Chem. Soc., Dalton Trans., 1998, 21.
  • Z.A.Starikova, E.P.Turevskaya, N.I.Kozlova et.al. Structural of zirconium and hafnium oxoalkoxides. Polyhedron,1999, 18, 941
  • E.P.Turevskaya, K.A.Vorotilov, V.B. Bergo et al. Sol-gel processing of bismuth stronitium tantalate thin films, J. Phys.IV France, 1998, 8, Pr 9-83.
  • E.P.Turevskaya, A.I.Belokon', Z.A.Starikova et al. Scandium alkoxides: the first mixed ligand alkoxides containing the [M5O(OR)8] core, scandium alkoxoaluminates, Polyhedron, 2000, 19, 705.
  • N.Ya.Turova, E.P.Turevskaya, V.G.Kessler, M.I.Yanovskaya The Chemistry of Metal Alkoxides. Kluwer Acad. Publishers, 2002.

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